The short answer is yes, you can generally make this swap, but it requires an understanding of how each ingredient behaves. If a recipe calls for one cup of vegetable oil, you should use one cup of olive oil.
Substitute Olive Oil for Vegetable Oil in Brownies: Flavor and Texture Tips
This is often desirable in cakes and muffins, as it helps retain moisture for a longer period, keeping the bake fresh longer. While baking usually occurs at lower temperatures than frying, the smoke point is still a relevant factor.
Texture and Moisture Considerations Both olive oil and vegetable oil are 100% fat, which means they contribute to the moistness and richness of the final product. Do not adjust the quantity, as this could disrupt the balance of wet to dry ingredients.
Olive Oil Swaps in Brownies: Flavor and Texture Tips
However, the molecular structure differs slightly. If a recipe calls for one cup of vegetable oil, you should use one cup of olive oil.
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